Surface, Particle & Porosity

Zeta Potential Measurement

Surface charge of particles by electrophoretic light scattering

Zeta potential measures the effective surface charge of particles in a liquid from how fast they move in an electric field. It is used to judge dispersion stability and how surfaces respond to pH or additives.

1 test optionElectrophoretic light scatteringResult in millivolts (mV)Typical turnaround 3–5 working days
Zeta Potential Measurement measurement principleIllustrative
Power supplyElectrodesDetectorLaserCharged particlesFolded capillary cellZeta distribution
Charge revealed by motion in a fieldIllustrative
01 / Overview

What is Zeta Potential Measurement?

An electric field is applied across the dispersion in a folded capillary cell. Charged particles drift towards the opposite electrode, and a laser measures their speed from the Doppler shift of the scattered light. The Henry equation converts this electrophoretic mobility into zeta potential.

The result reflects the charge at the slipping plane around each particle, which governs how strongly particles repel one another. As a rough guide, values beyond about ±30 mV suggest good stability, while values near zero point to aggregation.

02 / How it works

How it works

  1. 01

    Cell is filled

    About 1 mL of the dispersion is injected into a folded capillary cell, without air bubbles.

  2. 02

    Field is applied

    A voltage across the electrodes makes charged particles drift towards the opposite electrode.

  3. 03

    Laser tracks the motion

    Light scattered by the moving particles is Doppler-shifted; the frequency shift gives their speed.

  4. 04

    Zeta potential is calculated

    Mobility is converted to zeta potential with the Henry equation and reported as a distribution.

03 / What it measures

What it measures

Zeta potential (mV)

Size and sign of the effective surface charge in the liquid.

Useful forNanoparticles, colloids, emulsions

Electrophoretic mobility

How fast the particles move per unit of applied field.

Useful forComparing surface treatments and coatings

Dispersion stability

A larger magnitude, typically beyond ±30 mV, means stronger repulsion.

Useful forInks, slurries, suspensions and formulations

Zeta potential vs pH (on request)

Measurements across a pH range locate the isoelectric point.

Useful forOxide, pigment and protein surfaces
04 / Test options

Choose the Zeta Potential Measurement options you need

1 option · none added yet

Zeta Potential Measurement test options
05 / Sample requirements

Sample requirements

Accepted forms
Aqueous or polar-solvent dispersions, colloids, emulsions; powders with a named medium
Quantity
Typically 2–5 mL of dispersion, or 10–20 mg of powder
Concentration
Dilute, at most slightly turbid; state the concentration
Medium
State pH and salt content; very high conductivity limits the measurement
  • Well-dispersed, stable sample
  • State the dispersant, pH and any salts or surfactants
  • Say if a specific pH or dilution medium is needed
  • Leak-proof, labelled vials
  • No non-polar solvent dispersions without discussing first
  • No coarse or fast-settling suspensions

Hazardous or air-sensitive samples: mention it in your request, and attach the MSDS if you have one.

06 / Results & turnaround

Results & turnaround

What you receive

  • Mean zeta potential (mV) with standard deviation
  • Zeta potential distribution plot
  • Electrophoretic mobility and sample conductivity
  • Measurement conditions: medium, pH, temperature
  • Report PDF

Turnaround & pricing

Typically 3–5 working days after samples reach the lab.

Price confirmed in your quotation, depending on user type, options and number of samples.

Sample report · IllustrativeExample zeta potential−34.2 mVIllustrative — not measured sample data
07 / Limitations

When Zeta Potential Measurement isn't the right fit

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