Electrical, Magnetic & Electrochemical

Electrical Conductivity

Four Probe Method

The four-probe method passes a current through the outer two of four in-line probes and reads the voltage across the inner two. It gives sheet resistance, resistivity and conductivity without contact-resistance errors.

1 test optionSheet resistance & resistivityFilms, wafers and pelletsTypical turnaround 3–5 working days
Electrical Conductivity measurement principleIllustrative
Current sourceVoltmeterFour probesFilm, wafer or pelletVoltage vs current
Four points, one clean readingIllustrative
01 / Overview

What is Electrical Conductivity?

Four equally spaced probes are pressed onto the sample in a straight line. A known current flows between the outer pair while a high-impedance voltmeter reads the voltage across the inner pair. Geometric correction factors turn this into sheet resistance and, with the thickness, into resistivity and conductivity.

Because almost no current flows through the voltage probes, contact and lead resistance drop out of the result, unlike a simple two-probe measurement. It is quick, needs only a flat surface, and suits thin films, semiconductor wafers, conductive coatings and pressed powder pellets.

02 / How it works

How it works

  1. 01

    Sample is placed flat

    The film, wafer or pellet sits on an insulating stage with the measured side facing up.

  2. 02

    Probes touch down

    Four equally spaced, spring-loaded probes are lowered onto the surface in a straight line.

  3. 03

    Current flows, voltage is read

    A known current passes through the outer probes while the inner pair measures the voltage drop.

  4. 04

    Resistivity is calculated

    V/I is corrected for sample size and thickness to give sheet resistance, resistivity and conductivity.

03 / What it measures

What it measures

Sheet resistance

Resistance of a thin layer per square, independent of its size.

Useful forConductive films, TCOs, coatings

Resistivity

A material property, from sheet resistance and known thickness.

Useful forWafers, pellets, bulk sheets

Conductivity

The reciprocal of resistivity, reported in S/cm or S/m.

Useful forConductive polymers, composites, ceramics

Uniformity

Compare readings at several points on the same sample.

Useful forDeposited films, wafers

Effect of processing

Compare samples before and after annealing, doping or coating.

Useful forProcess and recipe optimisation
04 / Test options

Choose the Electrical Conductivity options you need

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Electrical Conductivity test options
05 / Sample requirements

Sample requirements

Accepted forms
Films on insulating substrates, wafers, sheets, pressed pellets
Size
Flat piece at least ~10 × 10 mm; pellets ~10–20 mm diameter
Thickness
State film or pellet thickness; it is needed for resistivity
Powders
Send as a pressed pellet, or discuss pelletising first
  • Flat, clean surface on the measured side
  • Films deposited on an insulating substrate (e.g. glass, quartz)
  • Note film or pellet thickness, if known
  • No films on conductive substrates without discussing first
  • No soft, sticky, wet or crumbling samples

Hazardous or air-sensitive samples: mention it in your request, and attach the MSDS if you have one.

06 / Results & turnaround

Results & turnaround

What you receive

  • Sheet resistance (Ω/sq)
  • Resistivity (Ω·cm) and conductivity (S/cm), with thickness
  • V–I data for each reading
  • Multi-point readings, when requested
  • Report PDF

Turnaround & pricing

Typically 3–5 working days after samples reach the lab.

Price confirmed in your quotation, depending on user type, options and number of samples.

Sample report · IllustrativeExample sheet resistance48 Ω/sqIllustrative — not measured sample data
07 / Limitations

When Electrical Conductivity isn't the right fit

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