Elemental & Composition

XRF

X-ray Fluorescence

XRF measures which elements a sample contains, and how much, from the characteristic X-rays they emit under an X-ray beam. It is fast and non-destructive, covering major elements down to ppm levels.

1 test optionElements typically Na to UMajor elements to ppm levelsTypical turnaround 3–5 working days
XRF measurement principleIllustrative
X-ray tubePrimary X-raysSample cupFluorescent X-raysDetectorEnergy spectrumCharacteristic X-ray
Each element answers at its own energyIllustrative
01 / Overview

What is XRF?

X-ray Fluorescence irradiates the sample with X-rays from a tube. They eject inner-shell electrons, and as outer electrons fill the vacancies each element emits fluorescent X-rays at its own characteristic energies. A detector sorts these by energy or wavelength, and peak intensities give concentrations.

XRF measures solids, pressed powders and liquids with little preparation and no acid digestion, so it is quicker than ICP for major and minor elements. It cannot detect the lightest elements (H to around F), is less sensitive than ICP-MS for trace metals, and gives no chemical-state or phase information.

02 / How it works

How it works

  1. 01

    Sample is prepared

    Powders are pressed into pellets or filled into a cup; solids are measured on a flat face.

  2. 02

    X-rays excite atoms

    Primary X-rays from the tube eject inner-shell electrons from atoms in the sample.

  3. 03

    Atoms fluoresce

    Outer electrons fill the vacancies, and each element emits X-rays at its own energies.

  4. 04

    Spectrum is quantified

    The detector sorts X-rays by energy; peak intensities are converted into concentrations.

03 / What it measures

What it measures

Elemental composition

Identify and quantify the elements present, typically Na to U.

Useful forUnknown materials, minerals, residues

Oxide composition

Report major elements as oxides such as SiO₂, Al₂O₃ and CaO.

Useful forCement, clays, glass, ceramics, ores

Heavy & toxic metals

Screen for elements such as Pb, Cd and Cr at ppm levels.

Useful forSoils, plastics, consumer products

Alloy composition

Check the major and alloying elements in metals.

Useful forSteels, brasses, aluminium alloys

Elements in liquids

Measure elements such as S, Cl or metals in oils and solutions.

Useful forOils, fuels, liquid products
04 / Test options

Choose the XRF options you need

1 option · none added yet

XRF test options
05 / Sample requirements

Sample requirements

Accepted forms
Powders, pressed pellets, flat solids, metal pieces, liquids
Powder quantity
Around 5–10 g preferred; a few grams can be run in a cup
Solid size
Flat face roughly 20–40 mm across
Liquids
About 10 mL in a sealed, leak-proof bottle
Particle size
Finely ground (roughly under 75 µm) for best accuracy
  • Dry, finely ground and well-mixed powder
  • Flat, clean surface on solid and metal pieces
  • List the elements of interest and expected levels
  • No volatile, flammable or corrosive liquids without discussing first
  • No wet or damp powders

Hazardous or air-sensitive samples: mention it in your request, and attach the MSDS if you have one.

06 / Results & turnaround

Results & turnaround

What you receive

  • XRF spectrum (intensity vs energy)
  • Detected elements list
  • Element or oxide concentrations (wt% / ppm)
  • Raw data files
  • Report PDF

Turnaround & pricing

Typically 3–5 working days after samples reach the lab.

Price confirmed in your quotation, depending on user type, options and number of samples.

Sample report · IllustrativeExample Fe₂O₃ content4.8 wt%Illustrative — not measured sample data
07 / Limitations

When XRF isn't the right fit

Let’s find your next step

Need help choosing an option?

Share what you want to measure. We’ll help you find the right next step.