Surface, Particle & Porosity

BET

Brunauer–Emmett–Teller Surface Area Analysis

BET measures the specific surface area of powders and porous solids from nitrogen adsorption at 77 K. It is the standard way to compare catalysts, adsorbents and battery materials.

4 test optionsN₂ adsorption at 77 KSurface area in m²/gTypical turnaround 4–6 working days
BET measurement principleIllustrative
N₂ gasDosing manifoldPressure gaugeSample tubePorous sampleLiquid N₂ at 77 KAdsorption isotherm
Every pore, counted by the gas it holdsIllustrative
01 / Overview

What is BET?

BET analysis cools a degassed sample in liquid nitrogen and doses it with nitrogen gas in small steps. The amount adsorbed at each pressure gives an isotherm, and the BET equation converts the monolayer capacity into a specific surface area.

Because gas molecules reach every open pore and crack, BET reports the full accessible surface rather than the outer particle size. Recording desorption as well gives total pore volume and a mesopore size distribution from the same run.

02 / How it works

How it works

  1. 01

    Sample is degassed

    The powder is heated under vacuum or gas flow to clear moisture and adsorbed gases from its pores.

  2. 02

    Cooled to 77 K

    The sample tube is lowered into liquid nitrogen so gas can adsorb on its surface.

  3. 03

    Gas is dosed step by step

    Known doses of nitrogen are admitted and the pressure is logged as the surface takes up gas.

  4. 04

    Surface area is calculated

    The BET equation is fitted to the low-pressure data for surface area; the full curve gives pore data.

03 / What it measures

What it measures

Specific surface area

Total accessible surface per gram, from a multipoint BET fit.

Useful forCatalysts, adsorbents, battery powders

Total pore volume

Pore volume from the gas taken up close to saturation pressure.

Useful forPorous supports, silicas, activated carbons

Pore size distribution (BJH)

Share of pore volume in each mesopore size range.

Useful forMesoporous materials, catalyst supports

Adsorption–desorption isotherm

The full curve; its hysteresis loop hints at pore shape.

Useful forComparing porous structures

Micropore area (t-plot)

Estimate how much of the surface lies in micropores.

Useful forZeolites, microporous carbons
04 / Test options

Choose the BET options you need

4 options · none added yet

BET test options
05 / Sample requirements

Sample requirements

Accepted forms
Dry powders, granules, pellets or small solid pieces
Quantity
Typically 0.2–1 g; up to 2–3 g for low-surface-area materials
Piece size
Must fit a sample tube with a ~9 mm neck; say if pieces may be crushed
Thermal stability
State the highest temperature the sample tolerates during degassing
  • Dry, free-flowing powder or small pieces
  • State the maximum safe degassing temperature
  • Send extra material for low-surface-area samples
  • Sealed, labelled containers
  • No liquids, slurries or wet pastes
  • No samples that melt or decompose below ~100 °C without discussing first

Hazardous or air-sensitive samples: mention it in your request, and attach the MSDS if you have one.

06 / Results & turnaround

Results & turnaround

What you receive

  • BET surface area (m²/g) with C constant and fit range
  • Adsorption–desorption isotherm plot
  • Pore volume and BJH pore size distribution, if ordered
  • Raw data files
  • Report PDF

Turnaround & pricing

Typically 4–6 working days after samples reach the lab.

Price confirmed in your quotation, depending on user type, options and number of samples.

Sample report · IllustrativeExample BET surface area412 m²/gIllustrative — not measured sample data
07 / Limitations

When BET isn't the right fit

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